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Ocean surface rain layers (RLs) form when relatively colder, fresher, less dense rain water stably stratifies the upper ocean. RLs cool sea surface temperature (SST) by confining surface evaporative cooling to a thin near‐surface layer, and generate sharp SST gradients between the cool RL and the surrounding ocean. In this study, ocean‐atmosphere coupled simulations of the November 2011 Madden‐Julian Oscillation (MJO) event are conducted with and without RLs to evaluate two pathways for RLs to influence the atmosphere. The first, termed the “SST gradient effect,” arises from the hydrostatic adjustment of the boundary layer to RL‐enhanced SST gradients. The second, termed the “SST effect,” arises from RL‐induced SST reductions impeding the development of deep atmospheric convection. RLs are found to sharpen SST gradients throughout the MJO suppressed and suppressed‐to‐enhanced convection transition phases, but their effect on convection is only detected during the MJO suppressed phase when RL‐induced SST gradients enhance low‐level convergence/divergence and broaden the atmospheric vertical velocity probability distribution below 5 km. The SST effect is more evident than the SST gradient effect during the MJO transition phase, as RLs reduce domain average SST by 0.03 K and narrow vertical velocity distribution, thus delaying onset of deep convection. A delayed SST effect is also identified, wherein frequent RLs during the MJO transition phase isolate accumulated subsurface ocean heat from the atmosphere. The arrival of strong winds at the onset of the MJO active phase erodes RLs and releases subsurface ocean heat to the atmosphere, supporting the development of deep convection.

 

Utilization of the interaction between spin and heat currents is the central focus of the field of spin caloritronics. Chiral phonons possessing angular momentum arising from the broken symmetry of a non-magnetic material create the potential for generating spin currents at room temperature in response to a thermal gradient, precluding the need for a ferromagnetic contact. Here we show the observation of spin currents generated by chiral phonons in a two-dimensional layered hybrid organic–inorganic perovskite implanted with chiral cations when subjected to a thermal gradient. The generated spin current shows a strong dependence on the chirality of the film and external magnetic fields, of which the coefficient is orders of magnitude larger than that produced by the reported spin Seebeck effect. Our findings indicate the potential of chiral phonons for spin caloritronic applications and offer a new route towards spin generation in the absence of magnetic materials. 

Abstract. In this work, we integrated the WAVEWATCH III model into the regional coupled model SKRIPS (Scripps–KAUST Regional Integrated Prediction System). The WAVEWATCH III model is implemented with flexibility, meaning the coupled system can run with or without the wave component. In our implementations, we considered the effect of Stokes drift, Langmuir turbulence, sea surface roughness, and wave-induced momentum fluxes. To demonstrate the impact of coupling we performed a case study using a series of coupled and uncoupled simulations of Tropical Cyclone Mekunu, which occurred in the Arabian Sea in May 2018. We examined the model skill in these simulations and further investigated the impact of Langmuir turbulence in the coupled system. Because of the chaotic nature of the atmosphere, we ran an ensemble of 20 members for each coupled and uncoupled experiment. We found that the characteristics of the tropical cyclone are not significantly different due to the effect of surface waves when using different parameterizations, but the coupled models better capture the minimum pressure and maximum wind speed compared with the benchmark stand-alone Weather Research and Forecasting (WRF) model. Moreover, in the region of the cold wake, when Langmuir turbulence is considered in the coupled system, the sea surface temperature is about 0.5 ∘C colder, and the mixed layer is about 20 m deeper. This indicates the ocean model is sensitive to the parameterization of Langmuir turbulence in the coupled simulations. 

Silicon monoxide (SiO) is classified as a key precursor and fundamental molecular building block to interstellar silicate nanoparticles, which play an essential role in the synthesis of molecular building blocks connected to the Origins of Life. In the cold interstellar medium, silicon monoxide is of critical importance in initiating a series of elementary chemical reactions leading to larger silicon oxides and eventually to silicates. To date, the fundamental formation mechanisms and chemical dynamics leading to gas phase silicon monoxide have remained largely elusive. Here, through a concerted effort between crossed molecular beam experiments and electronic structure calculations, it is revealed that instead of forming highly-stable silicon dioxide (SiO 2 ), silicon monoxide can be formed via a barrierless, exoergic, single-collision event between ground state molecular oxygen and atomic silicon involving non-adiabatic reaction dynamics through various intersystem crossings. Our research affords persuasive evidence for a likely source of highly rovibrationally excited silicon monoxide in cold molecular clouds thus initiating the complex chain of exoergic reactions leading ultimately to a population of silicates at low temperatures in our Galaxy.